By Augustus M. Filbert, Michael L. Hair (auth.), Mars G. Fontana, Roger W. Staehle (eds.)
This sequence used to be prepared to supply a discussion board for assessment papers within the region of corrosion. the purpose of those studies is to carry yes components of corrosion technological know-how and know-how right into a sharp concentration. The volumes of this sequence are released nearly on a each year foundation and every includes 3 to 5 reports. The articles in every one quantity are chosen in this sort of approach as to be of curiosity either to the corrosion scientists and the corrosion technologists. there's, actually, a specific target in juxtaposing those pursuits end result of the value of mutual interplay and interdisciplinarity so vital in corrosion reviews. it truly is was hoping that the corrosion scientists during this manner may possibly remain abreast of the actions in corrosion expertise and vice versa. during this sequence the time period "corrosion" is utilized in its very broadest experience. It comprises, for that reason, not just the degradation of metals in aqueous en vironment but additionally what's mostly known as "high-temperature oxidation. " additional, the plan is to be much more normal than those issues; the sequence will contain all solids and all environments. this day, engineering solids contain not just metals yet glasses, ionic solids, polymeric solids, and composites of those. Environments of curiosity has to be prolonged to liquid metals, a wide selection of gases, nonaqueous electrolytes, and different non aqueous liquids.
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Extra resources for Advances in Corrosion Science and Technology: Volume 5
18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. Augustus M. Filbert and Michael L. Hair E. B. Shand, Glass Engineering Handbook, McGraw-Hili, New York (1958). W. C. Taylor and R. D. Smith, J. Am. Ceram. Soc. 19,331 (1936). W. Stober, Kolloid-Z. 147, 131 (1956). W. Eitel, in Silicate Science, Vol. 4, Academic Press, New York (1966). W. Eitel, in Silicate Science, Vol. I, p. 320, Academic Press, New York (1964). G. B. Alexander, W.
This is shown in Fig. 11 for Hel attack at two temperatures. 52 Hydrofluoric acid is the outstanding exception 4 DURATION OF TEST (HR) Fig. 11. Solubility of a glass of low durability (sodium silicate) in 5 % Hel versus time. 22 Augustus M. Filbert and Michael L. Hair wF'-Si-O-Si-~ (a) -Si···O-Si- I F H Si O-Si- I I I (b) (e) Fig. 12. Hydrofluoric acid attack on Si-O-Si bond. to this general rule, and it attacks silicate glasses very readily. As with other acids, the nonbridging oxygens are presumably attacked by protons to form silanol groups, but the reaction rate is increased as a result of the simultaneous attack of the F- ion on the silicate structure, as shown in Fig.
HALOGEN CORROSION OF METALS Phillip L. Daniel Materials Technology Department Goodyear Atomic Corporation Piketon, Ohio and Robert A. Rapp Department of Metallurgical Engineering The Ohio State University Columbus, Ohio INTRODUCTION Halogens and many halogen compounds are very corrosive. In fact, iodine was discovered when, as an impurity in soda ash, it caused corrosion of copper vessels. 1 Hence, materials for containing and handling halogens and corrosive halogen compounds must be selected with particular care.